HomeChemistryC4: Organic ChemistryC4.3 Burning Hydrocarbons – Complete and Incomplete Combustion

C4: Organic Chemistry

C4.1 Introduction to Organic ChemistryC4.2 Crude Oil and Fractional DistillationC4.3 Burning Hydrocarbons – Complete and Incomplete CombustionC4.4 Alkanes and AlkenesC4.5 Addition Polymers
C4: Organic Chemistry

Burning Hydrocarbons – Complete and Incomplete Combustion

Understand the difference between complete and incomplete combustion and their environmental impacts

Gas flame combustion

Combustion Reactions

Complete vs Incomplete

Complete Combustion
Burning with excess oxygen

Complete combustion occurs when a hydrocarbon burns in excess oxygen. The only products are carbon dioxide (CO₂) and water (H₂O), plus energy in the form of heat and light. The flame is blue and produces no smoke or soot.

For example, methane burning completely: CH₄ + 2O₂ → CO₂ + 2H₂O. This is the ideal combustion reaction as it releases maximum energy and produces less harmful products (though CO₂ is still a greenhouse gas).

Key Exam Point

Complete combustion is identified by a blue flame and no soot. You can test for products: water condenses on cold glass, CO₂ turns limewater milky.

Incomplete Combustion
Burning with limited oxygen

Incomplete combustion occurs when there is insufficient oxygen for complete burning. The products include carbon monoxide (CO), carbon/soot (C), and water. The flame is orange or yellow and produces visible black smoke.

For example: CH₄ + O₂ → CO + 2H₂O or CH₄ + O₂ → C + 2H₂O. This releases less energy than complete combustion and produces toxic carbon monoxide.

Carbon monoxide is extremely dangerous because it's colourless and odourless. It binds to haemoglobin in red blood cells more strongly than oxygen, preventing oxygen transport. This can cause headaches, dizziness, and death. Faulty boilers and car exhausts are common sources.

Combustion Reaction Simulator
Adjust oxygen levels to see complete vs incomplete combustion
Complete
Flame: Blue (clean)

100% oxygen available

Reaction Equation

CH₄ + 2O₂ → CO₂ + 2H₂O

Products

CO₂Carbon dioxide (greenhouse gas)
H₂OWater vapour

Environmental impact: CO₂ is a greenhouse gas contributing to global warming. CO and soot cause air pollution and respiratory issues.

Environmental Effects
Impact of combustion products

Carbon dioxide (CO₂) is a greenhouse gas. It traps heat in Earth's atmosphere, contributing to global warming and climate change. Burning fossil fuels releases large amounts of CO₂.

Carbon monoxide (CO) is a toxic air pollutant that affects human health. Soot (carbon particles) causes air pollution, reduces visibility, and can trigger respiratory problems like asthma. Both are produced by incomplete combustion in car engines and poorly maintained heating systems.

Key Terms Flashcards
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Term
Complete Combustion
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Worked Example
Writing combustion equations

Question:

Write the balanced equation for complete combustion of propane (C₃H₈) and explain why incomplete combustion is dangerous.

Answer:

Complete combustion equation:

C₃H₈ + 5O₂ → 3CO₂ + 4H₂O

Balancing: 3 carbons produce 3 CO₂; 8 hydrogens produce 4 H₂O; this requires 10 oxygen atoms (5 O₂ molecules).

Why incomplete combustion is dangerous: It produces carbon monoxide (CO), which is colourless and odourless. CO binds to haemoglobin in the blood more strongly than oxygen, reducing the blood's ability to carry oxygen. This can cause headaches, unconsciousness, and death.

Test Your Knowledge
Question 1 of 6

What are the products of complete combustion?